Please note that this process is also covered by the Easy Steps component.
Make 3 entries in Transfer Transactions. The first, for the total paid to employees, will be From Bank To Employee Wages Account.
The second, for the Tax and NIC’s paid to HMRC, will be From Bills Unpaid To Employee Tax/NIC Account.
Then a third entry is entered when the payment is made to HMRC and is entered as From Bank To Bills Unpaid.
You can make as many of the first entry as you requried to cover each employee individually, or consolidate into a single transaction per payday.